N-Methyl-3,5-dinitrobenzamide

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N-Methyl-3,5-dinitro­benzamide

The asymmetric unit of the title compound, C(8)H(7)N(3)O(5), contains two independent mol-ecules in which the amide plane is oriented at dihedral angles of 29.82 (2) and 31.17 (2)° with respect to the benzene ring. In the crystal, mol-ecules are connected via inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.

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4-Methyl-N-phenyl­benzene­sulfonamide

In the title compound, C(13)H(13)NO(2)S, the dihedral angle between the aromatic rings is 68.4 (1)°. In the crystal, the molecules are linked into inversion dimers by pairs of N-H⋯O hydrogen bonds. The unit cell of this compound was reported previously [Oh et al. (1985 ▶). Chung. Kwa. Yong. (Chung. J. Sci.), 12, 67] but no atomic coordinates were established in the earlier study.

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In the structure of the title compound, C(11)H(13)NO(3), the conformations of the N-H and C=O bonds in the amide fragment are trans to each other. In the crystal, mol-ecules are linked into a 2(1) helical chain that propagates along the c axis through N-H⋯O inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811053888